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81 METAL FINISHING WASTEWATER TREATMENT INCORPORATING MATERIALS RECOVERY AND LOW TEMPERATURE EVAPORATION Ernest R. Ramirez, Director of Environmental Engineering Richard C. Ropp, Vice President of Technology Ramirez Associates, Inc. Far Hills, New Jersey 07931 INTRODUCTION The electroplating and metal finishing industries traditionally are operations that have low profit margins. This is especially true in the case of job shop operations where competitive bidding leads to minimized earnings. In order to keep capital costs down, many plants still operate electroplating equipment that is ten and even thirty years old. In general, innovation in this industry is not extensive because this involves capital funds which electroplaters usually do not have. While Federal EPA Effluent Limitations Guidelines for (non-integrated) Electroplating Point Source Category has mandated that this industry be in compliance by April 27, 1984, there is still a large number (perhaps 40%) of job shop operations which do not meet the USEPA Effluent Limitations Guidelines for Electroplating Point Source Category. The conventional heavy metal precipitation and cyanide destruction will cost (capital) a metal plater no less than $250,000 (installed), will occupy no less than 800 ft? of area, and last, but not least, will generate a sludge that must be manifested (expensive). Additionally, operating costs for the above wastewater treatment facility will vary annually from $25,000 to $50,000. There is no surprise that in view of the above, many metal platers are not in compliance with the effluent discharge limitations. This paper is a case study involving the design and engineering of a plating operation discharging 14,000 gpd. Metals involved are: chromium, nickel, copper and the cyanide ion. NEW WASTEWATER TREATMENT CONCEPT WHICH LOWERS PLANT OPERATING COSTS The new concept of wastewater treatment involves the operations of material recovery and low temperature evaporation. In reality these methodologies have been used and are still used by precious metal platers where materials recovery is paramount to their staying in business. This paper refers to the technology as new simply because platers have been unaware of its effectiveness, low capital costs and its overall contribution to reduced operating costs when chemical dragout volumes are large. This is typical in the barrel plating operations. Also, plating parts with blind holes will markedly lower operating costs due to the value of the recovered chemicals. In these two cases wastewater pretreatment would actually lower overall costs and raise profits, contrary to the metal finisher's normal perception. CONCEPT-MATERIALS RECOVERY WITH LOW TEMPERATURE EVAPORATION Materials Recovery The guiding principles in materials recovery are straightforward and simply entail the following concepts: • Contains all (99%) chemicals that leave the electroplating tank on the plated part. • Use still (non-flowing) dragout tanks directly in series with the electroplating tank. • The size and the number of dragout tanks will be determined by an engineering material balance encompassing the factors of: 1) parts plating load; and 2) the desired percentage of recovery (often set at 99%). • Each working day, the dragout tanks are pumped out once, as follows: 1) 1st dragout 679
Object Description
Purdue Identification Number | ETRIWC198681 |
Title | Metal finishing wastewater treatment incorporating material recovery and low temperature evaporation |
Author |
Ramirez, Ernest R. Ropp, Richard C. |
Date of Original | 1986 |
Conference Title | Proceedings of the 41st Industrial Waste Conference |
Conference Front Matter (copy and paste) | http://e-archives.lib.purdue.edu/u?/engext,37786 |
Extent of Original | p. 679-683 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital object copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Date Digitized | 2009-07-13 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Resolution | 300 ppi |
Color Depth | 8 bit |
Description
Title | page 679 |
Collection Title | Engineering Technical Reports Collection, Purdue University |
Repository | Purdue University Libraries |
Rights Statement | Digital copyright Purdue University. All rights reserved. |
Language | eng |
Type (DCMI) | text |
Format | JP2 |
Capture Device | Fujitsu fi-5650C |
Capture Details | ScandAll 21 |
Transcript | 81 METAL FINISHING WASTEWATER TREATMENT INCORPORATING MATERIALS RECOVERY AND LOW TEMPERATURE EVAPORATION Ernest R. Ramirez, Director of Environmental Engineering Richard C. Ropp, Vice President of Technology Ramirez Associates, Inc. Far Hills, New Jersey 07931 INTRODUCTION The electroplating and metal finishing industries traditionally are operations that have low profit margins. This is especially true in the case of job shop operations where competitive bidding leads to minimized earnings. In order to keep capital costs down, many plants still operate electroplating equipment that is ten and even thirty years old. In general, innovation in this industry is not extensive because this involves capital funds which electroplaters usually do not have. While Federal EPA Effluent Limitations Guidelines for (non-integrated) Electroplating Point Source Category has mandated that this industry be in compliance by April 27, 1984, there is still a large number (perhaps 40%) of job shop operations which do not meet the USEPA Effluent Limitations Guidelines for Electroplating Point Source Category. The conventional heavy metal precipitation and cyanide destruction will cost (capital) a metal plater no less than $250,000 (installed), will occupy no less than 800 ft? of area, and last, but not least, will generate a sludge that must be manifested (expensive). Additionally, operating costs for the above wastewater treatment facility will vary annually from $25,000 to $50,000. There is no surprise that in view of the above, many metal platers are not in compliance with the effluent discharge limitations. This paper is a case study involving the design and engineering of a plating operation discharging 14,000 gpd. Metals involved are: chromium, nickel, copper and the cyanide ion. NEW WASTEWATER TREATMENT CONCEPT WHICH LOWERS PLANT OPERATING COSTS The new concept of wastewater treatment involves the operations of material recovery and low temperature evaporation. In reality these methodologies have been used and are still used by precious metal platers where materials recovery is paramount to their staying in business. This paper refers to the technology as new simply because platers have been unaware of its effectiveness, low capital costs and its overall contribution to reduced operating costs when chemical dragout volumes are large. This is typical in the barrel plating operations. Also, plating parts with blind holes will markedly lower operating costs due to the value of the recovered chemicals. In these two cases wastewater pretreatment would actually lower overall costs and raise profits, contrary to the metal finisher's normal perception. CONCEPT-MATERIALS RECOVERY WITH LOW TEMPERATURE EVAPORATION Materials Recovery The guiding principles in materials recovery are straightforward and simply entail the following concepts: • Contains all (99%) chemicals that leave the electroplating tank on the plated part. • Use still (non-flowing) dragout tanks directly in series with the electroplating tank. • The size and the number of dragout tanks will be determined by an engineering material balance encompassing the factors of: 1) parts plating load; and 2) the desired percentage of recovery (often set at 99%). • Each working day, the dragout tanks are pumped out once, as follows: 1) 1st dragout 679 |
Resolution | 300 ppi |
Color Depth | 8 bit |
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